|Kiki and Luca|
|Nicknames||Liki, Kuca, Kica, Luki|
The relationship between Kiki and Luca Benedict. Luca first asked Kiki out in episode 106 Crushed but the date is cut short when Kiki started glowing uncontrollably. In episode 110 Circle of Friends they kiss for the first time. Kiki accidentally reveals her identity to Luca in episode Kiki Revealed and Luca feeling betrayed avoids her. In the episode Alien Attraction they become platonic friends again. It isn't until Heartbreak that they officially get back together. In Connection Kiki admits to having a personal connection with Luca.